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A temperature-resolved assembly of a series of the largest scandium-containing polyoxotungstates

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Abstract

We report a temperature-resolved assembly of a series of novel nanoscale hexameric Sc-containing polyoxometalates of {Sb6Sc11W60}, {Sb8Sc7W60}, and {Sb8Sc6W60}. These compounds include the largest Sc-containing polyoxotungstates and contain the largest number of Sc3+ ions of any polyoxotungstates reported to date.

Graphical abstract: A temperature-resolved assembly of a series of the largest scandium-containing polyoxotungstates

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Publication details

The article was received on 11 Mar 2017, accepted on 26 Apr 2017 and first published on 26 Apr 2017


Article type: Communication
DOI: 10.1039/C7DT00892A
Citation: Dalton Trans., 2017, Advance Article
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    A temperature-resolved assembly of a series of the largest scandium-containing polyoxotungstates

    Z. Cai, T. Yang, Y. Qi, X. Li and S. Zheng, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT00892A

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