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Bicyclo[2.2.2]octane-1,4-dicarboxylic acid: towards transparent metal–organic frameworks

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Abstract

The preparation of transparent porous materials can offer a different access towards the study of molecules under solid confined space. Metal–organic frameworks represent a unique opportunity due to their tunable pore size, however aromatic linkers present strong absorption and reduce the transparency. Herein, we report the first example of a MOF with bicyclic organic dicarboxylic linkers and its use as a solid solvent.

Graphical abstract: Bicyclo[2.2.2]octane-1,4-dicarboxylic acid: towards transparent metal–organic frameworks

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Publication details

The article was received on 09 Mar 2017, accepted on 10 May 2017 and first published on 10 May 2017


Article type: Communication
DOI: 10.1039/C7DT00855D
Citation: Dalton Trans., 2017, Advance Article
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    Bicyclo[2.2.2]octane-1,4-dicarboxylic acid: towards transparent metal–organic frameworks

    P. J. Llabres-Campaner, J. Pitarch-Jarque, R. Ballesteros-Garrido, B. Abarca, R. Ballesteros and E. García-España, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT00855D

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