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σ-Hammett Parameter: a Strategy to Enhance Both Photo- and Electro-luminescence Features of Heteroleptic Copper(I) Complexes

Abstract

Abstract: This work studies the effect of the σ-Hammett parameter (σp) – i.e., the σ-donation effect caused by substitution at the para position of the bipyridine ligand (4,4‘-R2bipy, where R is MeO, Me, H, NO2) – on both the photo- and electro-luminescence features of a series of heteroleptic copper(I) complexes – i.e., [Cu(N^N)(P^P)]+ where N^N and P^P ligands are R2bipy and Xantphos, respectively. In virtue of a comprehensive photophysical, theoretical, and thin-film lighting device – i.e., light-emitting electrochemical cells (LEC) – investigation, we note a clear relationship between the σp and the photo- and electro-luminescence parameters, such as photoluminescence quantum yields, excited-state lifetimes, and emission maxima, as well as device brightness, stability, and efficacy, respectively. As the most relevant finding, the substitution with the group featuring the most negative σp – i.e., MeO – provides a ca. five-fold enhancement of all of the aforementioned figures-of-merit upon comparison within the series of complexes. As such, this work provides a new guideline for a device optimization through a rational ligand design for heteroleptic copper(I) complexes.

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Supplementary files

Publication details

The article was received on 06 Mar 2017, accepted on 11 Apr 2017 and first published on 12 Apr 2017


Article type: Paper
DOI: 10.1039/C7DT00810D
Citation: Dalton Trans., 2017, Accepted Manuscript
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    σ-Hammett Parameter: a Strategy to Enhance Both Photo- and Electro-luminescence Features of Heteroleptic Copper(I) Complexes

    R. D. Costa, M. Viciano-Chumillas, J. Cano, M. D. wEBER and D. Armentano, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT00810D

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