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Organomagnesium amide catalyzed cross-dehydrocoupling of organosilanes with amines

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Abstract

The synthesis of novel heteroleptic organomagnesium(II) amide complexes [IMesMg(Ar){N(SiMe3)2}]; (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene), Ar = 2,6-Me2C6H3 (Xyl) (1) and 2,4,6-Me3C6H2 (Mes) (2) is reported. Both compounds 1 and 2 were confirmed by multinuclear (1H, 13C and 29Si) magnetic resonance spectroscopy, elemental analysis and single crystal X-ray structural analysis. Furthermore, the organomagnesium amide pre-catalyzed cross-dehydrogenative coupling of organosilanes with amines has been investigated.

Graphical abstract: Organomagnesium amide catalyzed cross-dehydrocoupling of organosilanes with amines

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Publication details

The article was received on 06 Mar 2017, accepted on 28 Mar 2017 and first published on 28 Mar 2017


Article type: Paper
DOI: 10.1039/C7DT00806F
Citation: Dalton Trans., 2017, Advance Article
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    Organomagnesium amide catalyzed cross-dehydrocoupling of organosilanes with amines

    A. Baishya, T. Peddarao and S. Nembenna, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT00806F

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