Jump to main content
Jump to site search

Issue 18, 2017
Previous Article Next Article

Organomagnesium amide catalyzed cross-dehydrocoupling of organosilanes with amines

Author affiliations

Abstract

The synthesis of novel heteroleptic organomagnesium(II) amide complexes [IMesMg(Ar){N(SiMe3)2}]; (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene), Ar = 2,6-Me2C6H3 (Xyl) (1) and 2,4,6-Me3C6H2 (Mes) (2) is reported. Both compounds 1 and 2 were confirmed by multinuclear (1H, 13C and 29Si) magnetic resonance spectroscopy, elemental analysis and single crystal X-ray structural analysis. Furthermore, the organomagnesium amide pre-catalyzed cross-dehydrogenative coupling of organosilanes with amines has been investigated.

Graphical abstract: Organomagnesium amide catalyzed cross-dehydrocoupling of organosilanes with amines

Back to tab navigation

Supplementary files

Publication details

The article was received on 06 Mar 2017, accepted on 28 Mar 2017 and first published on 28 Mar 2017


Article type: Paper
DOI: 10.1039/C7DT00806F
Citation: Dalton Trans., 2017,46, 5880-5887
  •   Request permissions

    Organomagnesium amide catalyzed cross-dehydrocoupling of organosilanes with amines

    A. Baishya, T. Peddarao and S. Nembenna, Dalton Trans., 2017, 46, 5880
    DOI: 10.1039/C7DT00806F

Search articles by author

Spotlight

Advertisements