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Complexes of Eu(III)(hfa)3 with a planar chiral P(III) ligand (Phanephos): solvent-sensitive sign inversion of circularly polarised luminescence

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Abstract

Complexes of Eu(III)(hfa)3 with a C2-symmetric planar P(III) ligand exhibited intense circularly polarised luminescence (CPL) due to 5D07F1 and 5D07F2 transitions, with the signs and shapes of CPL signals depending on the choice of solvent (acetone or chloroform).

Graphical abstract: Complexes of Eu(iii)(hfa)3 with a planar chiral P(iii) ligand (Phanephos): solvent-sensitive sign inversion of circularly polarised luminescence

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Publication details

The article was received on 28 Feb 2017, accepted on 14 Mar 2017, published on 14 Mar 2017 and first published online on 14 Mar 2017


Article type: Paper
DOI: 10.1039/C7DT00741H
Citation: Dalton Trans., 2017, Advance Article
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    Complexes of Eu(III)(hfa)3 with a planar chiral P(III) ligand (Phanephos): solvent-sensitive sign inversion of circularly polarised luminescence

    Y. Kono, N. Hara, M. Shizuma, M. Fujiki and Y. Imai, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT00741H

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