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Silver complexes stabilized by large silanethiolate ligands – crystal structures and luminescence properties

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Abstract

Bulky silanethiolate and disiladithiolate ligands were applied to synthesize one mononuclear and three trinuclear silver complexes including two cyclic “microclusters” and a linear tri-nuclear silanethiolate complex. All obtained compounds are characterized by X-ray diffraction and FT-IR. NMR and emission spectroscopies were used where possible. The first trinuclear anionic silver thiolate is structurally characterized. The influence of the different charge of cyclic silver complexes as well as the overall ligand environment on the structural properties is demonstrated. The impact of the different synthetic routes on the final structures of the obtained clusters – cyclic or linear – is discussed.

Graphical abstract: Silver complexes stabilized by large silanethiolate ligands – crystal structures and luminescence properties

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Publication details

The article was received on 28 Feb 2017, accepted on 26 Jul 2017 and first published on 27 Jul 2017


Article type: Paper
DOI: 10.1039/C7DT00740J
Citation: Dalton Trans., 2017, Advance Article
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    Silver complexes stabilized by large silanethiolate ligands – crystal structures and luminescence properties

    A. Ciborska, Z. Hnatejko, K. Kazimierczuk, A. Mielcarek, A. Wiśniewska and A. Dołęga, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT00740J

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