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First examples of tri- and tetraphosphametacyclophanes: synthesis and isolation of an unusual hexapalladium complex containing pincer units with Pd–P covalent bonds

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Abstract

The synthesis of the first examples of tri- and tetraphosphametacyclophanes [m-{–C(O)C5H3N(C(O)PPh)}3 (1) and m-{–C(O)C5H3N(C(O)PPh)}4 (2)] is described. The reaction of 1 with [Pd(η3-C3H5)Cl]2 yielded a rare hexapalladium(II) complex with four Pd–P covalent bonds.

Graphical abstract: First examples of tri- and tetraphosphametacyclophanes: synthesis and isolation of an unusual hexapalladium complex containing pincer units with Pd–P covalent bonds

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Publication details

The article was received on 28 Feb 2017, accepted on 20 Apr 2017 and first published on 21 Apr 2017


Article type: Communication
DOI: 10.1039/C7DT00737J
Citation: Dalton Trans., 2017, Advance Article
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    First examples of tri- and tetraphosphametacyclophanes: synthesis and isolation of an unusual hexapalladium complex containing pincer units with Pd–P covalent bonds

    V. S. Kashid, L. Radhakrishna and M. S. Balakrishna, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT00737J

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