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Frustrated Lewis pair behavior of a neutral scandium complex

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Abstract

An easily-accessible neutral scandium complex Sc[OC(CH3)2CH2PPh2][O-2,6-tBu2-C6H3]2[THF] behaves as a reactive Sc/P frustrated Lewis pair, which when added to organic and inorganic substrates e.g. carbonyl compounds, transition-metal chlorides, and diazoalkane compounds, yields unique and intriguing addition products such as a Sc/Rh heterobimetallic complex and a Sc phosphazine complex.

Graphical abstract: Frustrated Lewis pair behavior of a neutral scandium complex

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Publication details

The article was received on 23 Feb 2017, accepted on 02 Mar 2017, published on 09 Mar 2017 and first published online on 09 Mar 2017


Article type: Communication
DOI: 10.1039/C7DT00676D
Citation: Dalton Trans., 2017, Advance Article
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    Frustrated Lewis pair behavior of a neutral scandium complex

    K. Chang and X. Xu, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT00676D

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