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Synthesis of two titanosilicates with distinct interlayer connections from similar gels

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Abstract

Ti-SSZ-70 and Ti-ECNU-6, with identical intralayer structures but distinct interlayer connections, were prepared from similar synthetic gels free of alkali metal ions and boric acid. Ti-SSZ-70, composed of vertically misaligned MWW layers, was transferred to Ti-ECNU-6, structurally analogous to the Ti-MWW zeolite with a well-aligned layer stacking, upon the addition of an appropriate amount of hexamethyleneimine to the gel. These two titanosilicate catalysts exhibited outstanding catalytic activities in the liquid-phase alkene epoxidation.

Graphical abstract: Synthesis of two titanosilicates with distinct interlayer connections from similar gels

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Publication details

The article was received on 20 Feb 2017, accepted on 26 Mar 2017 and first published on 28 Mar 2017


Article type: Communication
DOI: 10.1039/C7DT00640C
Citation: Dalton Trans., 2017, Advance Article
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    Synthesis of two titanosilicates with distinct interlayer connections from similar gels

    P. Ji, K. Lu, X. Lu, H. Xu and P. Wu, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT00640C

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