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Issue 15, 2017
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A novel naphthalenediimide-based lanthanide–organic framework with polyoxometalate templates exhibiting reversible photochromism

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Abstract

The first visible-light-responsive photochromic polyoxometalate-templated lanthanide–organic framework (LOF) has been constructed from a carboxyphenyl-substituted naphthalenediimide (NDI) derivative, which displays an unusual four-fold interpenetration of an srs topological network, featuring a variety of anion–π interactions between polyoxoanions and π-acidic NDI moieties, and undergoes a rapid reversible photochromic transformation upon blue light irradiation.

Graphical abstract: A novel naphthalenediimide-based lanthanide–organic framework with polyoxometalate templates exhibiting reversible photochromism

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Publication details

The article was received on 20 Feb 2017, accepted on 13 Mar 2017 and first published on 20 Mar 2017


Article type: Communication
DOI: 10.1039/C7DT00631D
Citation: Dalton Trans., 2017,46, 4898-4901
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    A novel naphthalenediimide-based lanthanide–organic framework with polyoxometalate templates exhibiting reversible photochromism

    H. Zhang, J. Liao, W. Yang, X. Wu and C. Lu, Dalton Trans., 2017, 46, 4898
    DOI: 10.1039/C7DT00631D

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