Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance upgrade on Thursday 4th of May 2017 from 8.00am to 9.00am (BST).

During this time our websites will be offline temporarily. If you have any questions please use the feedback button on this page. We apologise for any inconvenience this might cause and thank you for your patience.



Functionalized vinylsilanes via highly efficient and recyclable Pt-nanoparticle catalysed hydrosilylation of alkynes

Author affiliations

Abstract

A mild, selective and facile synthesis of vinylsilanes via a recyclable platinum nanoparticle catalysed hydrosilylation of alkynes is reported. Various functionalized alkynes are selectively hydrosilylated to furnish functional β-E vinylsilanes in high yields. The catalytic effectiveness, ease of catalyst recovery and recyclability of the polysiloxane stabilized Pt-nanoparticle catalyst are the major achievements of this work. Detailed in situ characterization using Electron Microscopy and controlled poisoning experiments supports the participation of Pt-nanoparticles as active catalysts.

Graphical abstract: Functionalized vinylsilanes via highly efficient and recyclable Pt-nanoparticle catalysed hydrosilylation of alkynes

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 13 Feb 2017, accepted on 10 Apr 2017 and first published on 10 Apr 2017


Article type: Communication
DOI: 10.1039/C7DT00544J
Citation: Dalton Trans., 2017, Advance Article
  •   Request permissions

    Functionalized vinylsilanes via highly efficient and recyclable Pt-nanoparticle catalysed hydrosilylation of alkynes

    B. P. S. Chauhan and A. Sarkar, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT00544J

Search articles by author