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Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M–Si–H–Si four-membered ring

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Abstract

Hydrogen-bridged bis(silylene) complexes of ruthenium and iron were synthesized as the first examples of this type containing Group 8 metals and their rare four-membered ring structures and multi-center bonding interactions at the M–Si–H–Si moiety were clarified by NMR spectroscopy, X-ray crystallography and theoretical calculations.

Graphical abstract: Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M–Si–H–Si four-membered ring

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Publication details

The article was received on 10 Feb 2017, accepted on 06 Mar 2017 and first published on 17 Mar 2017


Article type: Communication
DOI: 10.1039/C7DT00505A
Citation: Dalton Trans., 2017, Advance Article
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    Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M–Si–H–Si four-membered ring

    H. Hashimoto, K. Komura, T. Ishizaki, Y. Odagiri and H. Tobita, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT00505A

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