Jump to main content
Jump to site search

Issue 27, 2017
Previous Article Next Article

Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M–Si–H–Si four-membered ring

Author affiliations

Abstract

Hydrogen-bridged bis(silylene) complexes of ruthenium and iron were synthesized as the first examples of this type containing Group 8 metals and their rare four-membered ring structures and multi-center bonding interactions at the M–Si–H–Si moiety were clarified by NMR spectroscopy, X-ray crystallography and theoretical calculations.

Graphical abstract: Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M–Si–H–Si four-membered ring

Back to tab navigation

Supplementary files

Publication details

The article was received on 10 Feb 2017, accepted on 06 Mar 2017 and first published on 17 Mar 2017


Article type: Communication
DOI: 10.1039/C7DT00505A
Citation: Dalton Trans., 2017,46, 8701-8704
  •   Request permissions

    Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M–Si–H–Si four-membered ring

    H. Hashimoto, K. Komura, T. Ishizaki, Y. Odagiri and H. Tobita, Dalton Trans., 2017, 46, 8701
    DOI: 10.1039/C7DT00505A

Search articles by author

Spotlight

Advertisements