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Issue 32, 2017
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Hollow hematite single crystals deposited with ultra-thin Al2O3 by atom layer deposition for improved photoelectrochemical performance

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Abstract

Hematite (α-Fe2O3) is a red material with a band gap of about 2.0 eV, which indicates that it can absorb more solar light. It is a promising photocatalyst applied in many fields. In this paper, α-Fe2O3 single crystal hollow hexagonal bipyramids were synthesized by a simple one-pot hydrothermal method. The morphology and structure of the prepared α-Fe2O3 hollow hexagonal bipyramids were studied using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The hollow single crystals show a good light absorption and performance in photodegradation of methylene blue (MB). Due to the strategy of depositing ultra-thin layers of Al2O3 by atomic layer deposition (ALD), the photoelectrochemical (PEC) performance of α-Fe2O3 under the simulated solar light irradiation is also improved.

Graphical abstract: Hollow hematite single crystals deposited with ultra-thin Al2O3 by atom layer deposition for improved photoelectrochemical performance

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Publication details

The article was received on 10 Feb 2017, accepted on 05 Apr 2017 and first published on 05 Apr 2017


Article type: Paper
DOI: 10.1039/C7DT00504K
Citation: Dalton Trans., 2017,46, 10635-10640
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    Hollow hematite single crystals deposited with ultra-thin Al2O3 by atom layer deposition for improved photoelectrochemical performance

    W. Jiao, J. Wu, S. Cui, N. Wei, Z. U. Rahman, M. Yu, S. Chen, Y. Zhou and D. Wang, Dalton Trans., 2017, 46, 10635
    DOI: 10.1039/C7DT00504K

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