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Organic–inorganic hybrid three-dimensional metal sulfite-oxalates with honeycomb-like structures

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Abstract

The crystallographic signatures and characterization of two novel mixed metal hybrid open-frameworks [Na2Mn2(C2O4)(SO3)2(H2O)2] 1 and [NaEu(C2O4)(SO3)(H2O)3] 2 are reported for the first time; they are synthesized under hydrothermal conditions to generate 3D assemblies and honeycomb-like structures. They were further characterized by complementary techniques like PXRD, TGA and DSC. The magnetic properties of 1 show antiferromagnetic interactions between the metal centers and compound 2 shows good photoluminescence properties.

Graphical abstract: Organic–inorganic hybrid three-dimensional metal sulfite-oxalates with honeycomb-like structures

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Publication details

The article was received on 08 Feb 2017, accepted on 28 Mar 2017 and first published on 28 Mar 2017


Article type: Paper
DOI: 10.1039/C7DT00477J
Citation: Dalton Trans., 2017, Advance Article
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    Organic–inorganic hybrid three-dimensional metal sulfite-oxalates with honeycomb-like structures

    R. K. Tiwari and J. N. Behera, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT00477J

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