Jump to main content
Jump to site search


Application of the Boron Center for Design a Covalently Bonded Closely Spaced Triad of Porphyrin-Fullerene Mediated by Dipyromethane

Abstract

Two novel triads had been designed through covalent bond connection of the boron dipyromethane (BODIPY), free base porphyrin (H2P) or zinc(II) porphyrin (ZnP) and N-methyl-2-phenyl-3,4-fulleropyrrolidine (C60) mediated by BODIPY. This closely spaced triad arrangement where porphyrin and fullerene are placed apart is anticipated to stabilize charge separation by separating the two radicals from each other. Two model polyads were synthetized with BODIPY and H2P or ZnP to investigate interaction between the two chromophores. Photo-excitation of the BODIPY triggered an efficient singlet energy transfer where the rates are found to be ~1010-1011 s-1. For triads with C60 fast electron transfer confirmed by detection of C60•‒ signature from femtosecond transient absorption (fs-TA) in ~0.4‒3 ps. The charge recombination is estimated to be in nanosecond window. This indicates the convenience of this arrangement for stabilizing charge separated state.

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 07 Feb 2017, accepted on 07 Apr 2017 and first published on 07 Apr 2017


Article type: Paper
DOI: 10.1039/C7DT00472A
Citation: Dalton Trans., 2017, Accepted Manuscript
  •   Request permissions

    Application of the Boron Center for Design a Covalently Bonded Closely Spaced Triad of Porphyrin-Fullerene Mediated by Dipyromethane

    D. GAO, S. Aly, P. Karsenti, G. Brisard and P. D. Harvey, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT00472A

Search articles by author