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Issue 15, 2017
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Synthesis of (NHC)Pd(salicylaldimine)Cl complexes through template-directed ortho-aromatic metaloxylation of NHC–palladacycles derived from arylimines

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Abstract

Reactions of imidazoliums with palladacycles afforded NHC–palladacycle complexes. The reactivity of the NHC–palladacycles was explored and the results demonstrated that they could be template-directed ortho-aromatic metaloxylated in the presence of tert-butyl hydroperoxide (TBHP), affording (NHC)Pd(salicylaldimine)Cl complexes. Furthermore, the NHC–palladacycles showed efficient catalytic activities toward the ortho-aromatic hydroxylation of arylimines.

Graphical abstract: Synthesis of (NHC)Pd(salicylaldimine)Cl complexes through template-directed ortho-aromatic metaloxylation of NHC–palladacycles derived from arylimines

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Publication details

The article was received on 02 Jan 2017, accepted on 14 Mar 2017 and first published on 15 Mar 2017


Article type: Paper
DOI: 10.1039/C7DT00007C
Citation: Dalton Trans., 2017,46, 5003-5007
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    Synthesis of (NHC)Pd(salicylaldimine)Cl complexes through template-directed ortho-aromatic metaloxylation of NHC–palladacycles derived from arylimines

    J. Yang, Dalton Trans., 2017, 46, 5003
    DOI: 10.1039/C7DT00007C

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