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Issue 5, 2017
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Azido- and amido-substituted gallium hydrides supported by N-heterocyclic carbenes

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Abstract

Despite recent advances in main group N-heterocyclic carbene (NHC) coordination chemistry, gallium hydrides remain, in large part, an unexplored area of research. In this paper we outline efficient routes to azide- and amido-functionalized gallium hydrides such as NHC·GaH2N3 and NHC·GaH2N(SiMe3)2 and explore these species as potential precursors to HGaNH complexes and bulk gallium nitride (GaN).

Graphical abstract: Azido- and amido-substituted gallium hydrides supported by N-heterocyclic carbenes

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Publication details

The article was received on 05 Dec 2016, accepted on 30 Dec 2016 and first published on 02 Jan 2017


Article type: Paper
DOI: 10.1039/C6DT04595B
Citation: Dalton Trans., 2017,46, 1406-1412
  • Open access: Creative Commons BY license
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    Azido- and amido-substituted gallium hydrides supported by N-heterocyclic carbenes

    A. K. Swarnakar, M. J. Ferguson, R. McDonald and E. Rivard, Dalton Trans., 2017, 46, 1406
    DOI: 10.1039/C6DT04595B

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