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Fundamental organometallic chemistry under bimetallic influence: driving β-hydride elimination and diverting migratory insertion at Cu and Ni

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Abstract

Bimetallic effects on stoichiometric β-hydride elimination and migratory insertion reactions were examined. Bimetallic reaction conditions drove β-hydride elimination at Cu, while bimetallic C–B elimination occurred in the absence of β-hydrogens. The inherent migratory insertion chemistry of alkynes at Ni was diverted under bimetallic reaction conditions to favor C–H deprotonation.

Graphical abstract: Fundamental organometallic chemistry under bimetallic influence: driving β-hydride elimination and diverting migratory insertion at Cu and Ni

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Publication details

The article was received on 30 Nov 2016, accepted on 13 Dec 2016, published on 14 Dec 2016 and first published online on 14 Dec 2016


Article type: Paper
DOI: 10.1039/C6DT04533B
Citation: Dalton Trans., 2017, Advance Article
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    Fundamental organometallic chemistry under bimetallic influence: driving β-hydride elimination and diverting migratory insertion at Cu and Ni

    T. J. Mazzacano, N. J. Leon, G. W. Waldhart and N. P. Mankad, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C6DT04533B

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