Jump to main content
Jump to site search

Issue 12, 2017
Previous Article Next Article

C–H⋯Cl hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands

Author affiliations

Abstract

Structural evidence is reported for C–H⋯Cl hydrogen bonds in solution and in the solid state of HgCl2 complexes with cyclen-based cryptands. These cyclen-based cryptands (1) and (2) are bridged by di- and triethylene glycol units, respectively, between two aromatic rings. The X-ray structure indicates that the 2/HgCl2 complex contains an acetonitrile molecule in the cavity.

Graphical abstract: C–H⋯Cl− hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands

Back to tab navigation

Supplementary files

Publication details

The article was received on 30 Aug 2016, accepted on 20 Jan 2017 and first published on 20 Jan 2017


Article type: Communication
DOI: 10.1039/C6DT03390C
Citation: Dalton Trans., 2017,46, 3800-3804
  •   Request permissions

    C–H⋯Cl hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands

    M. Ikeda, A. K. Sah, M. Iwase, R. Murashige, J. Ishi-i, M. Hasegawa, C. Kachi-Terajima, K. Park, S. Kuwahara and Y. Habata, Dalton Trans., 2017, 46, 3800
    DOI: 10.1039/C6DT03390C

Search articles by author

Spotlight

Advertisements