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Iridium(III)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

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Abstract

Cyclometallated iridium(III) complexes with 2-phenylpyridine [Ir(ppy)2(CNR)Cl] (ppy = (2-phenylpyridinato-C2,N), R = Xyl, Mes), [Ir(ppy)2(CNR)2](OTf) (R = Xyl, Mes), and fac-[Ir(ppy)3] catalyse the cross-linking of polysiloxanes exclusively at temperatures above 100 °C leading to luminescent rubbers.

Graphical abstract: Iridium(iii)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

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Publication details

The article was received on 30 Sep 2017, accepted on 01 Nov 2017 and first published on 01 Nov 2017


Article type: Communication
DOI: 10.1039/C7CY02013A
Citation: Catal. Sci. Technol., 2017, Advance Article
  • Open access: Creative Commons BY-NC license
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    Iridium(III)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

    R. M. Islamova, M. V. Dobrynin, A. V. Vlasov, A. A. Eremina, M. A. Kinzhalov, I. E. Kolesnikov, A. A. Zolotarev, E. A. Masloborodova and K. V. Luzyanin, Catal. Sci. Technol., 2017, Advance Article , DOI: 10.1039/C7CY02013A

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