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{[Cu3Lu2(ODA)6(H2O)6]·10H2O}n: the first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates

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Abstract

The catalytic performance of the novel framework {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O2) as oxidants. Excellent conversions were obtained with O2 under solvent-free conditions, in the absence of a co-catalyst, for cyclohexene (95%) and for cumene (91%).

Graphical abstract: {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n: the first heterometallic framework based on copper(ii)/lutetium(iii) for the catalytic oxidation of olefins and aromatic benzylic substrates

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Publication details

The article was received on 10 Jul 2017, accepted on 27 Sep 2017 and first published on 28 Sep 2017


Article type: Communication
DOI: 10.1039/C7CY01385J
Citation: Catal. Sci. Technol., 2017, Advance Article
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    {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n: the first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates

    P. Cancino, V. Paredes-García, J. Torres, S. Martínez, C. Kremer and E. Spodine, Catal. Sci. Technol., 2017, Advance Article , DOI: 10.1039/C7CY01385J

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