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Ni(II) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization

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Abstract

A Ni(II) catalyst incorporated into a new porous organic polymer, Ni(II)-POP-1, is prepared via a click reaction followed by metalation with NiCl2. It shows good catalytic activity for liquid-phase ethylene dimerization in the presence of Et2AlCl as a co-catalyst, generating 1-butene.

Graphical abstract: Ni(ii) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization

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Publication details

The article was received on 26 Jun 2017, accepted on 31 Aug 2017 and first published on 04 Sep 2017


Article type: Communication
DOI: 10.1039/C7CY01274H
Citation: Catal. Sci. Technol., 2017, Advance Article
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    Ni(II) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization

    M. J. Kim, S. Ahn, J. Yi, J. T. Hupp, J. M. Notestein, O. K. Farha and S. J. Lee, Catal. Sci. Technol., 2017, Advance Article , DOI: 10.1039/C7CY01274H

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