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Polystyrene supported palladium nanoparticles catalyzed cinnamic acid synthesis using maleic anhydride as a substitute for acrylic acid

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Abstract

Maleic anhydride was explored as a substitute for acrylic acid to synthesize cinnamic acids from aryl halides under heterogeneous palladium catalyzed conditions. The combined role of surface and impregnated catalyst together performed an upright engineering to hold in situ generated molecules on the surface and subsequently facilitate their interaction for the desired product synthesis. Overall, a surface mediated approach for cinnamic acid synthesis from maleic anhydride following a major unexplored pathway through catalyst promoted decarboxylation was critically investigated.

Graphical abstract: Polystyrene supported palladium nanoparticles catalyzed cinnamic acid synthesis using maleic anhydride as a substitute for acrylic acid

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Publication details

The article was received on 05 Jun 2017, accepted on 30 Jul 2017 and first published on 31 Jul 2017


Article type: Communication
DOI: 10.1039/C7CY01126A
Citation: Catal. Sci. Technol., 2017, Advance Article
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    Polystyrene supported palladium nanoparticles catalyzed cinnamic acid synthesis using maleic anhydride as a substitute for acrylic acid

    V. Thakur, S. Kumar and P. Das, Catal. Sci. Technol., 2017, Advance Article , DOI: 10.1039/C7CY01126A

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