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Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(II) and its derivatives

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Abstract

Simple nickel salts, bis(acetylacetonato)nickel(II) and its derivatives, catalysed the hydroboration reactions of aryl and alkyl nitriles with catechol borane. The reaction smoothly proceeded for nitriles with various substituents to form the corresponding bis(boryl)amines in good to excellent yields.

Graphical abstract: Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(ii) and its derivatives

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Publication details

The article was received on 12 May 2017, accepted on 29 May 2017 and first published on 30 May 2017


Article type: Communication
DOI: 10.1039/C7CY00944E
Citation: Catal. Sci. Technol., 2017, Advance Article
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    Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(II) and its derivatives

    G. Nakamura, Y. Nakajima, K. Matsumoto, V. Srinivas and S. Shimada, Catal. Sci. Technol., 2017, Advance Article , DOI: 10.1039/C7CY00944E

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