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A five coordination Cu(II) cluster-based MOF and its application in the synthesis of pharmaceuticals via sp3 C–H/N–H oxidative coupling

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Abstract

Herein, a copper metal–organic framework, termed as VNU-18, containing penta-coordinated sites was successfully synthesized and fully characterized. This material was demonstrated to be an efficient heterogeneous catalyst for the oxidative C–H activation via N–H bonds. The optimized conditions are applicable for the synthesis of pharmaceuticals constructed by α-amino carbonyl skeletons.

Graphical abstract: A five coordination Cu(ii) cluster-based MOF and its application in the synthesis of pharmaceuticals via sp3 C–H/N–H oxidative coupling

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Publication details

The article was received on 04 May 2017, accepted on 03 Jul 2017 and first published on 04 Jul 2017


Article type: Communication
DOI: 10.1039/C7CY00882A
Citation: Catal. Sci. Technol., 2017, Advance Article
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    A five coordination Cu(II) cluster-based MOF and its application in the synthesis of pharmaceuticals via sp3 C–H/N–H oxidative coupling

    T. V. Tran, H. T. N. Le, H. Q. Ha, X. N. T. Duong, L. H.-T. Nguyen, T. L. H. Doan, H. L. Nguyen and T. Truong, Catal. Sci. Technol., 2017, Advance Article , DOI: 10.1039/C7CY00882A

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