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Issue 14, 2017
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A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure

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Abstract

A simple and robust AgI/KOAc system was developed for the cyclization of propargyl alcohols and carbon dioxide under mild conditions, and was identified to have excellent activities for numerous substrates, especially sterically hindered terminal alkynes and internal alkynes. Notably, the Ag loading involved was an unprecedentedly low level of 0.05 mol%.

Graphical abstract: A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure

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Publication details

The article was received on 10 Apr 2017, accepted on 19 Jun 2017 and first published on 20 Jun 2017


Article type: Communication
DOI: 10.1039/C7CY00696A
Citation: Catal. Sci. Technol., 2017,7, 2935-2939
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    A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure

    Y. Yuan, Y. Xie, C. Zeng, D. Song, S. Chaemchuen, C. Chen and F. Verpoort, Catal. Sci. Technol., 2017, 7, 2935
    DOI: 10.1039/C7CY00696A

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