Jump to main content
Jump to site search


Synthesis of ene-yne-enes by nickel-catalyzed double SN2′ substitution of 1,6-dichlorohexa-2,4-diyne

Author affiliations

Abstract

1,6-Dichlorohexa-2,4-diyne undergoes nickel-catalyzed double substitution with aryl and alkenyl Grignard reagents to provide substituted ene-yne-enes. The reaction is formally an extension of the well-described SN2′-allylic and -propargylic substitution reactions but the mechanism is considerably more complex. The products might function as building blocks for conjugated polymers.

Graphical abstract: Synthesis of ene-yne-enes by nickel-catalyzed double SN2′ substitution of 1,6-dichlorohexa-2,4-diyne

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 06 Mar 2017, accepted on 26 Apr 2017 and first published on 26 Apr 2017


Article type: Paper
DOI: 10.1039/C7CY00429J
Citation: Catal. Sci. Technol., 2017, Advance Article
  •   Request permissions

    Synthesis of ene-yne-enes by nickel-catalyzed double SN2′ substitution of 1,6-dichlorohexa-2,4-diyne

    G. Wang, E. Lindeboom, C. van Heerewaarden and A. J. Minnaard, Catal. Sci. Technol., 2017, Advance Article , DOI: 10.1039/C7CY00429J

Search articles by author