Jump to main content
Jump to site search

Issue 9, 2017
Previous Article Next Article

Stereoselective access to trisubstituted fluorinated alkenyl thioethers

Author affiliations

Abstract

We report the first copper-catalyzed olefinic ethoxy carbonyl difluoromethylation of alkenyl thioethers via direct C–H bond functionalization using BrCF2COOEt. The developed methodology allows the preparation of trisubstituted olefins with a controlled stereochemistry. A mechanistic study is reported and a radical mechanism is revealed.

Graphical abstract: Stereoselective access to trisubstituted fluorinated alkenyl thioethers

Back to tab navigation

Supplementary files

Publication details

The article was received on 13 Jan 2017, accepted on 28 Mar 2017 and first published on 29 Mar 2017


Article type: Paper
DOI: 10.1039/C7CY00076F
Citation: Catal. Sci. Technol., 2017,7, 1921-1927
  •   Request permissions

    Stereoselective access to trisubstituted fluorinated alkenyl thioethers

    I. Fabre, T. Poisson, X. Pannecoucke, I. Gillaizeau, I. Ciofini and L. Grimaud, Catal. Sci. Technol., 2017, 7, 1921
    DOI: 10.1039/C7CY00076F

Search articles by author

Spotlight

Advertisements