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Stereoselective access to trisubstituted fluorinated alkenyl thioethers

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Abstract

We report the first copper-catalyzed olefinic ethoxy carbonyl difluoromethylation of alkenyl thioethers via direct C–H bond functionalization using BrCF2COOEt. The developed methodology allows the preparation of trisubstituted olefins with a controlled stereochemistry. A mechanistic study is reported and a radical mechanism is revealed.

Graphical abstract: Stereoselective access to trisubstituted fluorinated alkenyl thioethers

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Publication details

The article was received on 13 Jan 2017, accepted on 28 Mar 2017 and first published on 29 Mar 2017


Article type: Paper
DOI: 10.1039/C7CY00076F
Citation: Catal. Sci. Technol., 2017, Advance Article
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    Stereoselective access to trisubstituted fluorinated alkenyl thioethers

    I. Fabre, T. Poisson, X. Pannecoucke, I. Gillaizeau, I. Ciofini and L. Grimaud, Catal. Sci. Technol., 2017, Advance Article , DOI: 10.1039/C7CY00076F

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