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Issue 7, 2017
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Deep insight into Zr/Fe combination for successful Pt/CeO2/Al2O3 WGS catalyst doping

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Abstract

Efficient promotion of the Pt/CeO2/Al2O3 catalytic system was achieved by the addition of two different ceria promoters, Zr and Fe. From the exhaustive data analysis, the key features for enhanced catalytic performance and the roles of each doping metal are established. The combination of both doping agents manifests a synergistic effect reflected in noteworthy improvements in H2 reducibility. In addition, the catalyst's doping influences its chemisorptive properties, which is reflected in an increase of the easiness of carbonaceous species desorption, thus leading to superior catalyst resistance toward deactivation.

Graphical abstract: Deep insight into Zr/Fe combination for successful Pt/CeO2/Al2O3 WGS catalyst doping

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Publication details

The article was received on 06 Dec 2016, accepted on 25 Feb 2017 and first published on 28 Feb 2017


Article type: Paper
DOI: 10.1039/C6CY02551J
Citation: Catal. Sci. Technol., 2017,7, 1556-1564
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    Deep insight into Zr/Fe combination for successful Pt/CeO2/Al2O3 WGS catalyst doping

    M. González-Castaño, S. Ivanova, T. Ioannides, M. A. Centeno and J. A. Odriozola, Catal. Sci. Technol., 2017, 7, 1556
    DOI: 10.1039/C6CY02551J

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