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Metal–organic and covalent organic frameworks as single-site catalysts

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Abstract

Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions.

Graphical abstract: Metal–organic and covalent organic frameworks as single-site catalysts

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Publication details

The article was received on 17 Jan 2017 and first published on 24 Mar 2017


Article type: Review Article
DOI: 10.1039/C7CS00033B
Citation: Chem. Soc. Rev., 2017, Advance Article
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    Metal–organic and covalent organic frameworks as single-site catalysts

    S. M. J. Rogge, A. Bavykina, J. Hajek, H. Garcia, A. I. Olivos-Suarez, A. Sepúlveda-Escribano, A. Vimont, G. Clet, P. Bazin, F. Kapteijn, M. Daturi, E. V. Ramos-Fernandez, F. X. Llabrés i Xamena, V. Van Speybroeck and J. Gascon, Chem. Soc. Rev., 2017, Advance Article , DOI: 10.1039/C7CS00033B

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