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Issue 6, 2017
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Aryne multifunctionalization with benzdiyne and benztriyne equivalents

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Abstract

One of the most distinct characters of aryne chemistry over other synthetic methodologies is its ability to simultaneously functionalize the vicinal two positions of a benzene ring with diverse combinations of substituents. Moreover, the functionalization of the remaining four positions can be also achieved through multiaryne equivalents, in which more than one triple bond is generated on the different locations of the same benzene ring. This tutorial review summarizes the applications of benzdiyne and benztriyne equivalents from the standpoint of synthetic organic chemistry as well as in the preparation of polycyclic aromatic functional frameworks.

Graphical abstract: Aryne multifunctionalization with benzdiyne and benztriyne equivalents

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Publication details

The article was received on 22 Sep 2016 and first published on 20 Feb 2017


Article type: Tutorial Review
DOI: 10.1039/C6CS00694A
Citation: Chem. Soc. Rev., 2017,46, 1707-1719
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    Aryne multifunctionalization with benzdiyne and benztriyne equivalents

    J. Shi, Y. Li and Y. Li, Chem. Soc. Rev., 2017, 46, 1707
    DOI: 10.1039/C6CS00694A

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