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Issue 44, 2017
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A study on the diffusivity of polymers in crowded environments with periodically distributed nanoparticles

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Abstract

The effect of nanoparticles (NPs) on the diffusivity of polymers in crowded environments is complicated. We study the diffusivity of polymers in the environment with periodically distributed immobile NPs by using off-lattice Monte Carlo simulations. Results show that the diffusion coefficient D of polymers at low temperature is dependent on the inter-particle distance d and polymer length N or end-to-end distance of polymers in dilute solution R0. At low temperature, D is large at both small and large d and a minimum is observed at intermediate d. The nonmonotonic behavior of D is due to the reason that there are two kinds of diffusion modes for the polymers at low temperature: NP-exchange motion for R0 > d and adsorption-and-desorption motion for R0 < d. Moreover, we observe the oscillation of D with N at a relatively low temperature. The novel behavior is relevant to the adsorption of polymers on NPs and is explained from the free energy barrier for polymers jumping from the ground state to others.

Graphical abstract: A study on the diffusivity of polymers in crowded environments with periodically distributed nanoparticles

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Publication details

The article was received on 13 Aug 2017, accepted on 18 Oct 2017 and first published on 18 Oct 2017


Article type: Paper
DOI: 10.1039/C7CP05514E
Citation: Phys. Chem. Chem. Phys., 2017,19, 29975-29983
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    A study on the diffusivity of polymers in crowded environments with periodically distributed nanoparticles

    X. Huang, Y. Peng, J. Huang and M. Luo, Phys. Chem. Chem. Phys., 2017, 19, 29975
    DOI: 10.1039/C7CP05514E

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