Issue 42, 2017

The fountain effect of ice-like water across nanotubes at room temperature

Abstract

The well-known fountain effect of superfluid helium can directly convert heat to mechanical work by the transport of the superfluid across narrow channels under a temperature difference. But it is regarded as a unique feature of superfluids, only occurring below the temperature of 2.17 K. Here we report a peculiar fountain effect of ice-like water across nanotubes at room temperature. Based on molecular simulations, we observed fascinating ultrafast fountain flow across nanotubes from the cold side to the hot side under a small temperature difference, due to the near-dissipationless nature of ice-like ordered water inside the nanotubes. Water molecules exhibit collective behavior and spontaneously convert thermal energy from the surrounding into directed motion without dissipation. A surprising pressure difference of up to 256 bar is generated from a temperature difference of 23 K, almost reaching the thermodynamic limit. This finding is anticipated to provide a new protocol for power harvesting devices, heat engines and nanomotors.

Graphical abstract: The fountain effect of ice-like water across nanotubes at room temperature

Supplementary files

Article information

Article type
Communication
Submitted
12 Jul 2017
Accepted
13 Sep 2017
First published
13 Sep 2017

Phys. Chem. Chem. Phys., 2017,19, 28496-28501

The fountain effect of ice-like water across nanotubes at room temperature

K. Zhao and H. Wu, Phys. Chem. Chem. Phys., 2017, 19, 28496 DOI: 10.1039/C7CP04693F

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