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Issue 40, 2017
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Intriguing transport dynamics of ethylammonium nitrate–acetonitrile binary mixtures arising from nano-inhomogeneity

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Abstract

Binary mixtures of ethylammonium nitrate and acetonitrile show interesting properties that originate from the structural and dynamical nano-heterogeneity present in ionic liquids. These effects are most pronounced when the ionic liquid is the minority compound. In this study the transport properties of such mixtures are studied, including viscosity, self-diffusion and conductivity. The results strongly support the presence of structural inhomogeneity and show an interesting composition-dependent behaviour in the mixtures.

Graphical abstract: Intriguing transport dynamics of ethylammonium nitrate–acetonitrile binary mixtures arising from nano-inhomogeneity

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Publication details

The article was received on 08 Jul 2017, accepted on 18 Sep 2017 and first published on 18 Sep 2017


Article type: Paper
DOI: 10.1039/C7CP04592A
Citation: Phys. Chem. Chem. Phys., 2017,19, 27212-27220
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    Intriguing transport dynamics of ethylammonium nitrate–acetonitrile binary mixtures arising from nano-inhomogeneity

    A. Mariani, M. Bonomo, B. Wu, B. Centrella, D. Dini, E. W. Castner and L. Gontrani, Phys. Chem. Chem. Phys., 2017, 19, 27212
    DOI: 10.1039/C7CP04592A

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