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Emergent intramolecular hydrogen bonding effect to electronic structures of organic electron acceptors

Abstract

A new strategy for controlling the electron-accepting ability of an anthraquinone (AQ)-based π-molecular system is proposed to take advantage of intramolecular hydrogen bonding interactions. The electron-accepting properties of AQ are enhanced by the introduction of bulky arylsulfonamide groups into AQ derivatives due to the formation of effective intramolecular N-H•••O hydrogen bonding interaction and stabilization of the anion radical state even in solution.

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Publication details

The article was received on 30 Jun 2017, accepted on 07 Aug 2017 and first published on 07 Aug 2017


Article type: Communication
DOI: 10.1039/C7CP04402J
Citation: Phys. Chem. Chem. Phys., 2017, Accepted Manuscript
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    Emergent intramolecular hydrogen bonding effect to electronic structures of organic electron acceptors

    T. Takeda, Y. Suzuki, J. Kawamata, S. Noro, T. Nakamura and T. Akutagawa, Phys. Chem. Chem. Phys., 2017, Accepted Manuscript , DOI: 10.1039/C7CP04402J

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