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Increase in the reduction potential of uranyl upon interaction with graphene oxide surfaces

Abstract

Coordination of uranyl (U(VI)) with carboxylate groups on functionalized graphene oxide (GO) surfaces has been shown to alter the reduction potential of the sorbed uranium ion. A quantitative measure of the reduction potential and qualitative estimation of sorption/desorption processes was determined using cyclic voltammetry and a proposed coordination environment has been determined using surface sensitive attenuated total reflection mode of infrared spectroscopy (ATR-FTIR). GO is a nanostructured material possessing large amount of oxygen containing functional groups on both basal planes and the edges, which can form strong surface complexes with radionuclides. The presence of these functional groups on the surface of GO allows efficient immobilization of uranium due to sorption of uranyl (UO22+) to carboxylate, hydroxide, or sulfonate functional groups and the potential for enhanced reduction of U(VI) to more strongly sorbing and insoluble U(IV) . Binding of U(VI) to carboxylate groups on the GO surface is proposed as the primary sorption mechanism based on the FTIR study in this work. Furthermore, the coordination of uranium with the surface increases the reduction potential of the U(VI)/U(IV) redox couple relative to that of aqueous U(VI)/U(IV) species. This is consistent with the alteration of the electronic structure of the sorbed ion, which could be measured in our case due to the GO coated working electrode. Thus, GO coated glassy carbon electrodes and other semi-conducting electrodes with high ion sorption capacities may provide a means of examining the oxidation/reduction potentials of sorbed ions.

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Publication details

The article was received on 22 Jun 2017, accepted on 06 Dec 2017 and first published on 07 Dec 2017


Article type: Paper
DOI: 10.1039/C7CP04197G
Citation: Phys. Chem. Chem. Phys., 2017, Accepted Manuscript
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    Increase in the reduction potential of uranyl upon interaction with graphene oxide surfaces

    V. Bliznyuk, N. Conroy, Y. Xie, R. Podila, A. Rao and B. Powell, Phys. Chem. Chem. Phys., 2017, Accepted Manuscript , DOI: 10.1039/C7CP04197G

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