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Issue 28, 2017
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The role of O(1D) in the oxidation mechanism of ethylene by iodosobenzene and other hypervalent molecules

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Abstract

The role of the first excited state of oxygen (1D) is proven essential for the description of terminal iodine–oxygen chemical bonds. The description of the I–O bond as a dative one from iodine to O(1D) provides a simple and accurate picture which explains the oxidation properties of iodosobenzene and similar in nature molecules.

Graphical abstract: The role of O(1D) in the oxidation mechanism of ethylene by iodosobenzene and other hypervalent molecules

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Publication details

The article was received on 14 Jun 2017, accepted on 04 Jul 2017 and first published on 04 Jul 2017


Article type: Communication
DOI: 10.1039/C7CP04000H
Citation: Phys. Chem. Chem. Phys., 2017,19, 18152-18155
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    The role of O(1D) in the oxidation mechanism of ethylene by iodosobenzene and other hypervalent molecules

    S. N. Khan and E. Miliordos, Phys. Chem. Chem. Phys., 2017, 19, 18152
    DOI: 10.1039/C7CP04000H

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