Highly efficient hydrogen evolution reaction by strain and phase engineering in composites of Pt and MoS2 nano-scrolls

Abstract

The phase transition through local strain engineering is an exciting avenue for controlling electronic, magnetic properties and catalyst activity of materials but complex phenomenon in nanoscience. Herein, we demonstrate the first combinations of bending strain and 2H/1T phase transition by rolling up MoS₂ sheets for improving catalytic activity in relatively inert basal plane surfaces and promoting electron transfer from the less-conducting 2H MoS₂ sheets to the electrodes. Furthermore, we generate various MoS₂@Pt nanoparticle hybrids nanomaterials and especially MoS₂@Pt scrolls containing the coverage of Pt NPs (8.3 wt%) have a high catalytic activity (39 mV per decade). The rolled up MoS₂@Pt sheets with bending strain (2.4%) provide an intra-layer plane gliding that allows the transversal displacement of an S plane from the 2H to the 1T phases (28%). This unique combination also allows us to maximize the intrinsic HER activity among molybdenum-sulfide based catalysts.