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2D – 3D structural transition in sub-nanometer PtN clusters supported on CeO2(111)


Transition metal particles dispersed on oxide supports are used as heterogeneous catalysts in numerous applications. One example is platinum clusters supported on ceria which is used in automotive catalysis. Although control at the nm-scale is desirable to open new technological possibilities, limited knowledge is found both experimentally and theoretically regarding the geometrical structure and stability of sub-nanometer platinum clusters supported on ceria. Here we report a systematic, Density Functional Theory (DFT) study on the growth trends of CeO2(111) supported PtN clusters (N = 1 – 10). Using a global optimization methodology as a guidance tool to locate putative global minima (GM) configurations, our results show a clear preference for 2D planar structures up to size Pt8. It is followed by a structural transition to 3D configurations at larger sizes. This remarkable trend is explained by the subtle competition between the formation of strong Pt-O bonds and the cluster internal Pt-Pt bonds. Our calculations show that the reducibility of CeO2(111) provides a mechanism to anchor PtN cluster where they become oxidized in a two-way charge transfer mechanism: a) an oxidation process, where Osurface atoms withdraw charge from Pt atoms forming Pt-O bonds, b) surface Ce4+ atoms are reduced, leading to Ce3+. The active role of CeO2(111) support in modifying the structural eventually chemical properties of sub-nanometer PtN clusters is computationally demonstrated.

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Publication details

The article was received on 26 Apr 2017, accepted on 12 Jun 2017 and first published on 13 Jun 2017

Article type: Paper
DOI: 10.1039/C7CP02753B
Citation: Phys. Chem. Chem. Phys., 2017, Accepted Manuscript
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    2D – 3D structural transition in sub-nanometer PtN clusters supported on CeO2(111)

    L. O. Paz-Borbón, A. López-Martínez, I. L. Garzon, A. Posada-Amarillas and H. Gronbeck, Phys. Chem. Chem. Phys., 2017, Accepted Manuscript , DOI: 10.1039/C7CP02753B

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