Jump to main content
Jump to site search


Concave Binding of Cationic Li to Quadrannulene

Abstract

Binding of Li+ to quadrannulene and the influence on buckybowl functionalization are introduced. The concave-trapped Li+ acts as a Lewis acid and the rate of Diels-Alder cycloaddition is enhanced by 108 times. A sandwiched bowl-Li+-bowl structure is stabilized via concave-cation-convex interactions, indicating the promoted role of Li+ in buckybowl assembly.

Back to tab navigation

Supplementary files

Publication details

The article was received on 18 Apr 2017, accepted on 13 Jul 2017 and first published on 14 Jul 2017


Article type: Paper
DOI: 10.1039/C7CP02512B
Citation: Phys. Chem. Chem. Phys., 2017, Accepted Manuscript
  •   Request permissions

    Concave Binding of Cationic Li to Quadrannulene

    J. Dang, W. Wang, X. Zhao and S. Nagase, Phys. Chem. Chem. Phys., 2017, Accepted Manuscript , DOI: 10.1039/C7CP02512B

Search articles by author

Spotlight

Advertisements