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Issue 28, 2017
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Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study

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Abstract

A high resolution X-ray diffraction study has been carried out on [(C4H9)4N]2 [V6O13{(OCH2)3CCH2OCCH2CH3}2] (V6–C3) at 100 K. The V6 core possesses a negative charge, leading to a strong polarization of the anion. A nucleophilic region localized near the organic moiety and an electrophilic region in the vicinity of the V6 core provide an overall description of charge-transfer behavior.

Graphical abstract: Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study

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Publication details

The article was received on 22 Mar 2017, accepted on 15 Jun 2017 and first published on 15 Jun 2017


Article type: Communication
DOI: 10.1039/C7CP01840A
Citation: Phys. Chem. Chem. Phys., 2017,19, 18162-18166
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    Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study

    X. Xu, A. Spasojević-de Biré, N. E. Ghermani, Y. Wei, S. Novaković, N. Bošnjaković-Pavlović and P. Wu, Phys. Chem. Chem. Phys., 2017, 19, 18162
    DOI: 10.1039/C7CP01840A

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