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Issue 15, 2017
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A quantum-rovibrational-state-selected study of the Image ID:c7cp00937b-t1.gif reaction in the collision energy range of 0.05–10.00 eV: translational, rotational, and vibrational energy effects

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Abstract

We report detailed absolute integral cross sections (σ's) for the quantum-rovibrational-state-selected ion–molecule reaction Image ID:c7cp00937b-t3.gif in the center-of-mass collision energy (Ecm) range of 0.05–10.00 eV, where (v+1v+2v+3) = (000), (100), and (020), and Image ID:c7cp00937b-t4.gif. Three product channels, HCO+ + OH, HOCO+ + H, and CO+ + H2O, are identified. The measured σ(HCO+) curve [σ(HCO+) versus Ecm plot] supports the hypothesis that the formation of the HCO+ + OH channel follows an exothermic pathway with no potential energy barriers. Although the HOCO+ + H channel is the most exothermic, the σ(HOCO+) is found to be significantly lower than the σ(HCO+). The σ(HOCO+) curve is bimodal, indicating two distinct mechanisms for the formation of HOCO+. The σ(HOCO+) is strongly inhibited at Ecm < 0.4 eV, but is enhanced at Ecm > 0.4 eV by (100) vibrational excitation. The Ecm onsets of σ(CO+) determined for the (000) and (100) vibrational states are in excellent agreement with the known thermochemical thresholds. This observation, along with the comparison of the σ(CO+) curves for the (100) and (000) states, shows that kinetic and vibrational energies are equally effective in promoting the CO+ channel. We have also performed high-level ab initio quantum calculations on the potential energy surface, intermediates, and transition state structures for the titled reaction. The calculations reveal potential barriers of ≈0.5–0.6 eV for the formation of HOCO+, and thus account for the low σ(HOCO+) and its bimodal profile observed. The Ecm enhancement for σ(HOCO+) at Ecm ≈ 0.5–5.0 eV can be attributed to the direct collision mechanism, whereas the formation of HOCO+ at low Ecm < 0.4 eV may involve a complex mechanism, which is mediated by the formation of a loosely sticking complex between HCO+ and OH. The direct collision and complex mechanisms proposed also allow the rationalization of the vibrational inhibition at low Ecm and the vibrational enhancement at high Ecm observed for the σ(HOCO+).

Graphical abstract: A quantum-rovibrational-state-selected study of the reaction in the collision energy range of 0.05–10.00 eV: translational, rotational, and vibrational energy effects

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Publication details

The article was received on 12 Feb 2017, accepted on 14 Mar 2017 and first published on 15 Mar 2017


Article type: Paper
DOI: 10.1039/C7CP00937B
Citation: Phys. Chem. Chem. Phys., 2017,19, 9778-9789
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    A quantum-rovibrational-state-selected study of the Image ID:c7cp00937b-t1.gif reaction in the collision energy range of 0.05–10.00 eV: translational, rotational, and vibrational energy effects

    Y. Xu, B. Xiong, Y. Chang, Y. Pan, P. K. Lo, K. C. Lau and C. Y. Ng, Phys. Chem. Chem. Phys., 2017, 19, 9778
    DOI: 10.1039/C7CP00937B

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