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Issue 13, 2017
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Pressure inverse solubility and polymorphism of an edible γ-cyclodextrin-based metal–organic framework

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Abstract

A very exceptional effect of pressure-induced dissolution has been revealed for an edible metal–organic framework, γ-CD-MOF-1, formed using γ-cyclodextrin and KOH base. In addition, a new polymorph of γ-CD-MOF-1 has been obtained. The trigonal structure is a symmetry sub-group modification of the cubic form. The pressure-induced dissolution of γ-CD-MOF-1 and its polymorphism are shown to be closely related and regulated by adsorption in the pores, as well as the guest framework interactions.

Graphical abstract: Pressure inverse solubility and polymorphism of an edible γ-cyclodextrin-based metal–organic framework

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Publication details

The article was received on 26 Jan 2017, accepted on 27 Feb 2017 and first published on 03 Mar 2017


Article type: Paper
DOI: 10.1039/C7CP00593H
Citation: Phys. Chem. Chem. Phys., 2017,19, 9086-9091
  • Open access: Creative Commons BY-NC license
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    Pressure inverse solubility and polymorphism of an edible γ-cyclodextrin-based metal–organic framework

    E. Patyk-Kaźmierczak, M. R. Warren, D. R. Allan and A. Katrusiak, Phys. Chem. Chem. Phys., 2017, 19, 9086
    DOI: 10.1039/C7CP00593H

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