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Issue 18, 2017
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Oxygen thermomigration in acceptor-doped perovskite

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The recent proposal of possible oxygen-thermomigration as a plausible mechanism for unipolar resistive switching of oxide memristors is now widely employed in modelling or simulating their memristive function on the grounds of the conventional picture that the mobile component O is always thermophobic, with its reduced heat-of-transport being equal to its migrational enthalpy (qO* = ΔHm > 0). At 1000 °C, we measured the thermomigration of mobile-component O in a prototype memristive perovskite, CaTi0.90Sc0.10O2.95+δ, across its near-stoichiometric regime (δ ≈ 0), where oxygen vacancy concentration is essentially fixed by doping acceptor impurities (i.e., Image ID:c7cp00384f-t1.gif). It has been found that the reduced heat-of-transport of mobile O (qO*) varies systematically in the range of −2 < qO*/eV ≤ +2, as the composition varies from hypo-(δ < 0) to hyper-stoichiometry (δ > 0), exhibiting a sign reversal or thermomigration direction change from thermophilic (qO* < 0) to thermophobic (qO* > 0). This sign-reversal is attributed to the change in the electronic ambipolar company of Image ID:c7cp00384f-t2.gif from electrons to holes crossing the stoichiometric composition δ = 0. The numerical data for qO* together with the measurement details are reported.

Graphical abstract: Oxygen thermomigration in acceptor-doped perovskite

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Publication details

The article was received on 18 Jan 2017, accepted on 28 Mar 2017 and first published on 19 Apr 2017

Article type: Paper
DOI: 10.1039/C7CP00384F
Citation: Phys. Chem. Chem. Phys., 2017,19, 11120-11130
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    Oxygen thermomigration in acceptor-doped perovskite

    D. Shin and H. Yoo, Phys. Chem. Chem. Phys., 2017, 19, 11120
    DOI: 10.1039/C7CP00384F

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