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Issue 10, 2017
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Non-covalent π–π stacking interactions turn off non-adiabatic effects in proton-coupled electron transfer reactions

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Abstract

π–π stacking interactions do not necessarily change the mechanism involved in the H transfer reaction between phenol and phenoxyl radicals. We propose that, in such cases, the e is transferred between the π delocalized moieties, while the H+ is transferred between the donor and acceptor atoms.

Graphical abstract: Non-covalent π–π stacking interactions turn off non-adiabatic effects in proton-coupled electron transfer reactions

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Publication details

The article was received on 17 Dec 2016, accepted on 20 Feb 2017 and first published on 20 Feb 2017


Article type: Communication
DOI: 10.1039/C6CP08610A
Citation: Phys. Chem. Chem. Phys., 2017,19, 6969-6972
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    Non-covalent π–π stacking interactions turn off non-adiabatic effects in proton-coupled electron transfer reactions

    L. Muñoz-Rugeles, A. Galano and J. Raúl Alvarez-Idaboy, Phys. Chem. Chem. Phys., 2017, 19, 6969
    DOI: 10.1039/C6CP08610A

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