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Co–Co and Co–Fe cyano-bridged pentanuclear clusters based on a methylpyrazinyl-diamine tetradentate ligand: spin crossover and metal substitution effects

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Abstract

A pentanuclear CoII–CoIII cluster complex has been developed by a solvothermal synthesis. Its highly stable metal-mixed iron–cobalt derivatives display robust spin crossover (T1/2 = 268 K) controlled by the degree of substitution.

Graphical abstract: Co–Co and Co–Fe cyano-bridged pentanuclear clusters based on a methylpyrazinyl-diamine tetradentate ligand: spin crossover and metal substitution effects

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Publication details

The article was received on 20 Oct 2017, accepted on 09 Nov 2017 and first published on 09 Nov 2017


Article type: Communication
DOI: 10.1039/C7CE01826F
Citation: CrystEngComm, 2017, Advance Article
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    Co–Co and Co–Fe cyano-bridged pentanuclear clusters based on a methylpyrazinyl-diamine tetradentate ligand: spin crossover and metal substitution effects

    B. Fei, J. Zhou, Z. Yan, S. I. Shylin, V. Ksenofontov, I. A. Gural'skiy and X. Bao, CrystEngComm, 2017, Advance Article , DOI: 10.1039/C7CE01826F

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