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Pre-design and synthesis of a five-fold interpenetrated pcu-type porous coordination polymer and its CO2/CO separation

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Abstract

From the viewpoint of mathematics and topology, we proposed a rational design and stabilized the first five-fold interpenetrated porous coordination polymer (PCP) with a pcu topology and extra-framework volume (60.0%) by employing a linear ligand with the length of ∼2 nm. The resulting compound exhibits good CO2 uptake, enabling highly selective separation of CO2 from CO2/CO mixtures.

Graphical abstract: Pre-design and synthesis of a five-fold interpenetrated pcu-type porous coordination polymer and its CO2/CO separation

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Publication details

The article was received on 14 Sep 2017, accepted on 28 Oct 2017 and first published on 30 Oct 2017


Article type: Communication
DOI: 10.1039/C7CE01649B
Citation: CrystEngComm, 2017, Advance Article
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    Pre-design and synthesis of a five-fold interpenetrated pcu-type porous coordination polymer and its CO2/CO separation

    H. Cao, S. Wang, Y. Wang, H. Lyu, R. Krishna, Z. Lu, J. Duan and W. Jin, CrystEngComm, 2017, Advance Article , DOI: 10.1039/C7CE01649B

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