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Issue 30, 2017
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Luminescent sensing and photocatalytic degradation properties of an uncommon (4,5,5)-connected 3D MOF based on 3,5-di(3′,5′-dicarboxylphenyl)benzoic acid

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Abstract

An uncommon microporous metal–organic framework (MOF), {[Zn5(L)2(DMF)23-H2O)]·2DMF} (1), was successfully constructed using a less exploited symmetrical pentacarboxylate ligand, 3,5-di(3′,5′-dicarboxylphenyl)benzoic acid (H5L). The MOF 1 features a trinodal (4,5,5)-connected topology having a Schläfli symbol of (42·63·8)(45·65)2(46·64) and is stable in air as well as in acidic/basic aqueous media at room temperature. The MOF 1 behaves as a luminescent sensor for the highly selective and sensitive detection of Fe3+, Fe2+, Cu2+ and Ag+ ions and o-nitrophenol (MNP), p-nitrophenol (PNP), 2,4-dinitrophenol (DNP), 2,4,6-trinitrophenol (TNP) and 4-nitrotoluene (4-NT). Furthermore, the photocatalytic properties of 1 for the degradation of Methyl violet (MV) and Rhodamine B (RhB) have been explored. The possible quenching of the emissions of 1 in the presence of nitroaromatics has been addressed by theoretical calculations and the photocatalytic activity of 1 against organic dyes has been addressed using density of states (DOS) calculations.

Graphical abstract: Luminescent sensing and photocatalytic degradation properties of an uncommon (4,5,5)-connected 3D MOF based on 3,5-di(3′,5′-dicarboxylphenyl)benzoic acid

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Publication details

The article was received on 30 May 2017, accepted on 01 Jul 2017 and first published on 03 Jul 2017


Article type: Paper
DOI: 10.1039/C7CE01012E
Citation: CrystEngComm, 2017,19, 4368-4377
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    Luminescent sensing and photocatalytic degradation properties of an uncommon (4,5,5)-connected 3D MOF based on 3,5-di(3′,5′-dicarboxylphenyl)benzoic acid

    J. Jin, X. Wu, Z. Luo, F. Deng, J. Liu, A. Singh and A. Kumar, CrystEngComm, 2017, 19, 4368
    DOI: 10.1039/C7CE01012E

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