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Issue 32, 2017
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Assembly of supertetrahedral clusters into a Cu–In–S superlattice via an unprecedented vertex–edge connection mode

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Abstract

We demonstrated here the first case of a vertex–edge connection mode in a three-dimensional open-framework chalcogenide built from the largest known T5 cluster. Such connection relies on a tri-coordinated edge sulfur atom, which serves as the linkage to bridge two adjacent T5 clusters. The architecture of the resulting structure can be classified as the infinite order of super-supertetrahedral T5 clusters (T5, ∞).

Graphical abstract: Assembly of supertetrahedral clusters into a Cu–In–S superlattice via an unprecedented vertex–edge connection mode

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Publication details

The article was received on 05 May 2017, accepted on 24 Jul 2017 and first published on 24 Jul 2017


Article type: Communication
DOI: 10.1039/C7CE00849J
Citation: CrystEngComm, 2017,19, 4709-4712
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    Assembly of supertetrahedral clusters into a Cu–In–S superlattice via an unprecedented vertex–edge connection mode

    H. Wang, H. Yang, W. Wang, C. Xue, Y. Zhang, M. Luo, D. Hu, J. Lin, D. Li and T. Wu, CrystEngComm, 2017, 19, 4709
    DOI: 10.1039/C7CE00849J

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