Jump to main content
Jump to site search

Issue 31, 2017
Previous Article Next Article

A series of transition metal coordination polymers based on a rigid bi-functional carboxylate–triazolate tecton

Author affiliations

Abstract

By utilizing the pre-designed bi-functional ligand 4-{bis(4-benzoic)amino}-4H-1,2,4-triazole (H2L), five new transition-metal-based coordination polymers, namely, {[Zn(L)]·H2O·DMA}n (1), {[Zn2(L)2]·DMF}n (2),{[Mn(L)]·DMF}n (3), {[Cd(L)]·DMA}n (4) and [Cu3(OH)2(L)2]n (5) have been constructed and structurally characterized. In 1, the tetrahedral zinc ion was incorporated in the final structure. However, complexes 2, 3 and 4 bear 1D Zn-, Mn- and Cd-chains composed of metal ions, triazole and carboxyl groups, respectively. Differently, 1D [Cu43-OH)2] chains had been stabilized in the 3D structure of 5. In addition, the luminescence or magnetic properties of 1–5 had been correspondingly investigated with the consideration of their crystal structure. The whole research results manifest that utilizing a bi-functional ligand containing carboxyl and triazole groups is an efficient building method in constructing functional CPs.

Graphical abstract: A series of transition metal coordination polymers based on a rigid bi-functional carboxylate–triazolate tecton

Back to tab navigation

Supplementary files

Publication details

The article was received on 27 Apr 2017, accepted on 06 Jul 2017 and first published on 06 Jul 2017


Article type: Paper
DOI: 10.1039/C7CE00808B
Citation: CrystEngComm, 2017,19, 4586-4594
  •   Request permissions

    A series of transition metal coordination polymers based on a rigid bi-functional carboxylate–triazolate tecton

    N. Mao, P. Hu, F. Yu, X. Chen, G. Zhuang, T. Zhang and B. Li, CrystEngComm, 2017, 19, 4586
    DOI: 10.1039/C7CE00808B

Search articles by author

Spotlight

Advertisements